The Two Types of Fluoride: Calcium Fluoride vs. Sodium Fluoride – What You Need to Know
- Coach Eric Alex

- Oct 14, 2024
- 4 min read
Updated: Nov 16, 2024

When it comes to fluoride, most people don’t realize that there are two distinct types: calcium fluoride and sodium fluoride. While both are commonly associated with dental health, these two forms of fluoride come from very different sources and have drastically different impacts on your body. In this article, we’ll explore where each type of fluoride comes from, why calcium fluoride is considered safe, and why sodium fluoride is something you should be cautious of.
What is Calcium Fluoride?
Calcium fluoride is a naturally occurring compound found in many water sources, including underground wells and spring water. It is formed when calcium ions bind with fluoride ions. Because calcium binds with fluoride, this form is relatively insoluble and not as easily absorbed by the body, which makes it less toxic in natural amounts.
Where is Calcium Fluoride Found?
Calcium fluoride is naturally present in groundwater and in certain foods, like tea. It’s even found in some calcium-rich mineral deposits. This form of fluoride is generally considered to be safe because it exists naturally in the environment and is not associated with harmful effects when consumed in low amounts.

Is Calcium Fluoride Safe?
Since calcium fluoride occurs naturally in water and is found in small amounts, it’s considered beneficial in strengthening teeth and bones when ingested in appropriate levels. The key here is that calcium helps buffer the fluoride’s effect, making it less harmful to your body. Additionally, it is much less likely to build up in toxic levels within the body.
What is Sodium Fluoride?
On the other hand, sodium fluoride is a synthetic compound. It does not occur naturally and is most often found as a byproduct of industrial processes such as aluminum and phosphate fertilizer production. It’s this form of fluoride that is commonly added to tap water supplies, toothpastes, and mouthwashes under the guise of promoting dental health.
Where is Sodium Fluoride Found?
Sodium fluoride is commonly found in municipal water supplies, where it is added in controlled amounts as part of water fluoridation programs. It’s also a common ingredient in many over-the-counter dental products, including toothpaste, mouthwash, and even some dental treatments.

Why is Sodium Fluoride Unsafe?
Unlike calcium fluoride, sodium fluoride is highly soluble and easily absorbed by the body. This raises significant concerns because it can accumulate in your tissues over time, especially in bones and the pineal gland. exposure to sodium fluoride has been linked to a range of health issues, including:
Fluorosis – a condition that damages the enamel of the teeth, leading to discoloration and decay.
Skeletal fluorosis – excessive fluoride can accumulate in bones, making them brittle and more prone to fractures.
Neurological effects – some studies suggest that high levels of fluoride, especially sodium fluoride, may affect cognitive development, particularly in children.
Toxic byproducts – Because sodium fluoride is derived from industrial waste, it can carry other harmful byproducts that are not present in naturally occurring calcium fluoride.
Why You Should Be Cautious of Sodium Fluoride
The biggest issue with sodium fluoride is that it is an industrial byproduct and not a naturally occurring compound. While proponents claim it helps prevent tooth decay, there are growing concerns about its overall safety, especially with long-term exposure. Given that it is so readily absorbed by the body, it’s important to be cautious of your intake.
Here’s why you should be mindful of sodium fluoride:
Industrial Origins: Sodium fluoride is often a waste product of industries like aluminum manufacturing. It’s a man-made chemical, unlike calcium fluoride, which occurs naturally.
Accumulation in the Body: Sodium fluoride is easily absorbed into tissues, especially bones, where it can build up over time, potentially leading to long-term health problems like bone weakness.
Toxicity Concerns: High levels of sodium fluoride have been associated with various health risks, from dental and skeletal fluorosis to potential impacts on brain health.

How to Reduce Your Exposure to Sodium Fluoride
While calcium fluoride is relatively harmless and naturally found in many foods and water sources, you might want to limit your exposure to sodium fluoride. Here are some tips:
Use fluoride-free toothpaste: There are many fluoride-free options available that clean teeth without the risks associated with sodium fluoride.
Filter your drinking water: Some water filters are designed to remove fluoride from your drinking water, reducing your exposure.
Eat organic foods: Fluoride can be found in pesticides, so choosing organic options reduces the chance of exposure.
Read labels: Be mindful of dental products, as many contain sodium fluoride.
Final Thoughts
While fluoride is widely promoted as beneficial for dental health, it’s important to understand the differences between calcium fluoride and sodium fluoride. Calcium fluoride, found naturally in water and food, is generally safe and even beneficial in small amounts. Sodium fluoride, however, is a synthetic byproduct with potential health risks that shouldn’t be ignored.
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